No, you can't really do that. Your best option is to buy some attiny85 chips and turn one of your digisparks in to a littlewire usb programmer. You can then use that digispark to upload programs directly in to attiny85 chips without a bootloader.
Trying to hack the bootloader on a digispark to do something like that will just be painful and wont really work as well as you want.
While you're working on your project you can leave the littlewire attached to your chip - it wont interfere with the chip's functioning, and unlike the digispark, when you choose upload in the digispark arduino software it will automatically reset the chip and upload the program - no need to unplug and replug. All you do is go in to Tools > Programmer > USBtinyISP to use the littlewire instead of the digispark bootloader for program uploads.